Evaluation of the effect of adding hydrogen peroxide as an oxidizing agent in the cyanide leaching process to improve gold recovery
DOI:
https://doi.org/10.26439/ing.ind2026.n50.8636Keywords:
adsorption, cyanidation, gold, hydrogen peroxide, sodium cyanideAbstract
The objective of this study was to evaluate the effect of adding hydrogen peroxide (H2O2) as an oxidizing agent in cyanide leaching to improve gold recovery. Three tests were conducted, progressively adding three different volumes of 50 % H2O2 (60, 75, and 90 mL) over the 12-hour process, along with three volumes of NaCN (198, 188, and 158 mL). A control of 198 mL of NaCN (10 %) was added. It was observed that increasing the H2O2 addition decreased NaCN consumption and increased total gold content. The recovery was carried out using activated carbon to adsorb the metal. In the control, 1,82 g/m³ was obtained; in test 1, 1,86 g/m³; in test 2, 2,05 g/m³; and in test 3, 2,75 g/m³. NaCN consumption decreased to: control 256 mL/h, test 1: 198 mL/h, test 2: 188 mL/h, and test 3: 158 mL/h. The increase in H2O2 was 25 % in each of the tests. In conclusion, the addition of hydrogen peroxide favors a decrease in NaCN consumption in the process and increases the Au recovery percentages.
Downloads
References
Baharun, N., Ling, O. P., Ardani, M. R., Ariffin, K. S., Yaraghi, A., Abdullah, N. S., Putra, T. A. R., & Ismail, S. (2020). Effect of hydrogen peroxide and lead (II) nitrate on gold cyanide leaching of Malaysian mesothermal deposit gold ore. Physicochemical Problems of Mineral Processing, 56(5), 905-918. https://doi.org/10.37190/PPMP/126629
Baloyi, N. P., Nheta, W., Sibanda, V., & Safari, M. (2024). Mineralogical Insights into PGM Recovery from Middle Group (1-4) Chromite Tailings. Minerals, 14(9), 924. https://doi.org/10.3390/min14090924
Barton, I. F., & Hiskey, J. B. (2022). Chalcopyrite leaching in novel lixiviants. Hydrometallurgy, 207, 105775. https://doi.org/10.1016/j.hydromet.2021.105775
Buitrón, O., D., Barona, D., D., Iturra, M., F., & León, F., J. (2021). Validación del método para la determinación de oro por ensayo al fuego combinado con espectrometría de absorción atómica en muestras geológicas mineras metalúrgicas. InfoANALÍTICA, 9(1), 119-136. https://doi.org/10.26807/ia.v9i1.188
Costa, F. R., Nery, G. P., Carneiro, C. D. C., Kahn, H., & Ulsen, C. (2022). Mineral characterization of low-grade gold ore to support geometallurgy. Journal of Materials Research and Technology, 21, 2841-2852. https://doi.org/10.1016/j.jmrt.2022.10.085
Duru, N., & Nesbitt, C. (2021). Remediation of reduced sulfur species effects on gold and silver recovery during cyanide leaching. Hydrometallurgy, 205, 105756. https://doi.org/10.1016/j.hydromet.2021.105756
Flores, D. J., Graber, T. A., Angel-Castillo, A. H., Hernández, P. C., & Taboada, M. E. (2025). Use of Hydrogen Peroxide as Oxidizing Agent in Chalcopyrite Leaching: A Review. Metals, 15(5), 531. https://doi.org/10.3390/met15050531
Guzman, L., Segarra, M., Chimenos, J. M., Fernandez, M. A., & Espiell, F. (1999). Gold cyanidation using hydrogen peroxide. Hydrometallurgy, 52(1), 21-35. https://doi.org/10.1016/S0304-386X(99)00006-7
Karppinen, A., Seisko, S., Nevatalo, L., Wilson, B. P., Yliniemi, K., & Lundström, M. (2024). Gold recovery from cyanidation residue by chloride leaching and carbon adsorption–Preliminary results from CICL process. Hydrometallurgy, 226, 106304. https://doi.org/10.1016/j.hydromet.2024.106304
Kenzhaliyev, B., Surkova, T., Koizhanova, A., Yessimova, D., Amanzholova, L., & Dosymbayeva, Z. (2023). Study of the cyanide leaching of gold from low-grade raw materials in the presence of amino acids. Inorganics, 11(12), 461. https://doi.org/10.3390/inorganics11120461
Knorre, H., Loroesch, J., Gos, S., Stoll, M., & Ziegler, A. (1993). Process for leaching precious metals with hydrogen-peroxde and a cyande leaching solution (Patente estadounidense n.º 5250272). Oficina de Patentes y Marcas de los Estados Unidos. https://patents.google.com/patent/US5250272A/en
Layza Laban, C. N., & Pretell Villalobos, L. A. (2024). Optimización de dosificación de peróxido de hidrógeno y cianuro en la prelixiviación de mineral sulfurado para recuperar oro y plata [Tesis de licenciatura, Universidad Nacional de Trujillo]. Repositorio Universidad Nacional de Trujillo. https://hdl.handle.net/20.500.14414/22592
Liu, Z., Guo, X., Tian, Q., & Zhang, L. (2022). A systematic review of gold extraction: fundamentals, advancements, and challenges toward alternative lixiviants. Journal of Hazardous Materials, 440, 129778. https://doi.org/10.1016/j.jhazmat.2022.129778
Malacatus. (2023). Estudio de impacto ambiental y plan de manejo ambiental de las concesiones mineras los ríos Uno código 300814 y los ríos Tres código 300947, para las fases de exploración y explotación bajo régimen de pequeña minería, provincias: El Oro-Azuay. Ministerio de Ambiente de Ecuador. https://maatecalidadambiental.ambiente.gob.ec/index.php/2026/02/05/estudio-de-impacto-ambiental-y-plan-de-manejo-ambiental-de-las-concesiones-mineras-los-rios-uno-codigo-300814-y-los-rios-tres-codigo-300947-para-las-fases-de-exploracion-y-explotacion-bajo-r/
Malyshev, V., Karimova, L., Sagatbek, S., Kharchenko, Y., & Magaz, A. (2025). A comparative study of gold leaching kinetics using alternative reagents from concentrates of low-grade ores. Minerals, 15(3), 282. https://doi.org/10.3390/min15030282
Munganyinka, J. P., Habinshuti, J. B., Komadja, G. C., Uwamungu, P., Tanvar, H., Ofori-Sarpong, G., Mishra, B., Onwualu, A. P., & Shuey, S. (2022). Optimization of gold dissolution parameters in acidified thiourea leaching solution with hydrogen peroxide as an oxidant: implications of roasting pretreatment technology. Metals, 12(10), 1567. https://doi.org/10.3390/met12101567
Nava-Alonso, F., Elorza-Rodríguez, E., Uribe-Salas, A., & Pérez-Garibay, R. (2007). Análisis químico de cianuro en el proceso de cianuración: revisión de los principales métodos. Revista de Metalurgia, 43(1), 20-28. https://revistademetalurgia.revistas.csic.es/index.php/revistademetalurgia/article/view/48/48
Nourmohamadi, H., & Rezai, B. (2022). Comparative study of oxidants in gold cyanidation: A molecular picture. Minerals Engineering, 189, 107870. https://doi.org/10.1016/j.mineng.2022.107870
Nunan, T. O., Viana, I. L., Peixoto, G. C., Ernesto, H., Verster, D. M., Pereira, J. H., Bonfatti, J. M., & Cesar Teixeira, L. A. (2017). Improvements in gold ore cyanidation by pre-oxidation with hydrogen peroxide. Minerals Engineering, 108, 67-70. https://doi.org/10.1016/j.mineng.2017.01.006
Senanayake, G. (2006). The cyanidation of silver metal: Review of kinetics and reaction mechanism. Hydrometallurgy, 81(2), 75-85. https://doi.org/10.1016/j.hydromet.2005.12.001
Surimbayev, B., Yessengarayev, Y., Khumarbekuly, Y., Bolotova, L., Kanaly, Y., Akzharkenov, M., & Zhumabai, S. (2024). Effect of sodium acetate additive on gold leaching with cyanide solution: Laboratory and semi-pilot leaching tests. Heliyon, 10(15), e35805. https://doi.org/10.1016/j.heliyon.2024.e35805
Surimbayev, B., Yessengarayev, Y., Khumarbekuly, Y., Bolotova, L., Kanaly, Y., Zhumabai, S., & Akzharkenov, M. (2026). Influence of hydrogen peroxide and sodium acetate on gold cyanidation: laboratory and pilot-scale tests. Mining, Metallurgy and Exploration, 43, 1497-1509. https://doi.org/10.1007/s42461-025-01460-5
Valarezo Tenesaca, E. I., Astudillo Echeverría, J. S., Ordóñez Paladinez, V. D., Cuenca Vaca, A. B., & Leon Cueva, W. P. (2024). Reactivos usados para mejorar la lixiviación del oro con cianuro: una revisión. Ciencia Latina. Revista Científica Multidisciplinar, 8(3), 10874-10892. https://doi.org/10.37811/cl_rcm.v8i3.12248
Wang, S., Gong, C., Wang, H., Xia, X., Liu, J., & Lu, H. (2025). Determination of gold content in rock gold ore samples based on closed water bath aqua regia digestion-polyurethane foam enrichment and using flame atomic absorption spectrometry. RSC Advances, 15(26), 20724-20733. https://doi.org/10.1039/d5ra02280k
Yessengarayev, Ye. K., Surimbayev, B. N., Baimbetov, B. S., Mamyachenkov, S. V., & Kanaly, T. S. (2021). Ore treatment hydrogen peroxide during heap leaching of gold. Complex Use of Mineral Resources, 1(316), 5-14. https://doi.org/10.31643/2021/6445.01
Zhang, Y., Cui, M., Qiao, S., Liu, X., & Lyu, X. (2022). Extraction of gold from a gold concentrate using a lixiviant synthesized by a roasting process. Hydrometallurgy, 211, 105874. https://doi.org/10.1016/j.hydromet.2022.105874
Zhang, Y., Cui, M., Wang, J., Liu, X., & Lyu, X. (2022). A review of gold extraction using alternatives to cyanide: focus on current status and future prospects of the novel eco-friendly synthetic gold lixiviants. Minerals Engineering, 176, 107336.









